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Applied Intelligence - With the development of sensor and communication technology, industrial systems have accumulated a large amount of data. This data has provided new perspectives and methods... 相似文献
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Jinchen Wei Lilai Jiang Menglin Huang Yuning Wu Shiyou Chen 《Advanced functional materials》2021,31(42):2104913
It is believed that promoting the fraction of ferroelectric orthorhombic phase (o-phase) through O-poor growth conditions can increase the spontaneous polarization of HfO2 and (Hf,Zr)O2 thin films. However, the first-principles calculations show that the growth may be limited by the easy formation of point defects in the orthorhombic and tetragonal phases of HfO2, ZrO2, and (Hf,Zr)O2. Their dominant defects, O interstitial (Oi) under O-rich conditions and O vacancy (VO) under O-poor condition, have low formation energies and quite high density (1016–1019 cm−3 for 800–1400 K growth temperature). Especially, Oi has negative formation energy in tetragonal HfO2 under O-rich condition, causing non-stoichiometry and limiting the crystalline-seed formation during o-phase growth. High-density defects can cause disordering of dipole moments and increase leakage current, both diminishing the polarization. These results explain the experimental puzzle that the measured polarization is much lower than the ideal value even in O-poor thin films and highlight that controlling defects is as important as promoting the o-phase fraction for enhancing ferroelectricity. The O-intermediate condition (average of O-rich and O-poor conditions) and low growth temperature are proposed for fabricating HfO2 and (Hf,Zr)O2 with fewer defects, lower leakage current, and stronger ferroelectricity, which challenges the belief that O-poor condition is optimal. 相似文献
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A shale gas gathering and transportation pipeline in a good block in Sichuan Province started leaking after less than a year of operation. To investigate the causes of corrosion of the sulfate-reducing bacteria (SRB), optical microscopy, scanning electron microscopy, and X-ray diffraction were used to analyze the corrosion and perforation of the shale gas surface pipeline in conjunction with bacterial corrosion simulation experiments. The results showed that the pipeline material (L360N) conformed to the requirements of the American Petroleum Institute 5 L standard and that extracellular polymeric substances were present in the corrosion pits. The corrosion products mainly included FeCO3, FeS, CaCO3, MgCO3, and Fe mineralization. At 40°C, the uniform corrosion rate of L360N in the simulation experiment was 0.234 mm/a, and the local corrosion rate was 0.458 mm/a. SRB, saprophytes, and iron bacteria were detected in the on-site water medium and corrosion products, indicating that the main causes of shale gas pipeline corrosion are bacterial and CO2 corrosion. 相似文献
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Graphene-based heterostructure composite is a new type of advanced sensing material that includes composites of graphene with noble metals/metal oxides/metal sulfides/polymers and organic ligands. Exerting the synergistic effect of graphene and noble metals/metal oxides/metal sulfides/polymers and organic ligands is a new way to design advanced gas sensors for nitrogen-containing gas species including NH3 and NO2 to solve the problems such as poor stability, high working temperature, poor recovery, and poor selectivity. Different fabrication methods of graphene-based heterostructure composite are extensively studied, enabling massive progress in developing chemiresistive-type sensors for detecting the nitrogen-containing gas species. With the components of noble metals/metal oxides/metal sulfides/polymers and organic ligands which are composited with graphene, each material has its attractive and unique electrical properties. Consequently, the corresponding composite formed with graphene has different sensing characteristics. Furthermore, working ambient gas and response type can affect gas-sensitive characteristic parameters of graphene-based heterostructure composite sensing materials. Moreover, it requires particular attention in studying gas sensing mechanism of graphene-based heterostructure composite sensing materials for nitrogen-containing gas species. This review focuses on related scientific issues such as material synthesis methods, sensing performance, and gas sensing mechanism to discuss the technical challenges and several perspectives. 相似文献
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Luo Xin Yufeng Zhang Wenshan Duan Mingyan Ai Hongbo Song Qun Huang Jiankang Lu 《International Journal of Food Science & Technology》2022,57(5):2646-2655
Oil, accounting for 45% of almonds, is easily oxidised and can further induce the protein oxidation to reduce their quality. Structure and physicochemical properties of amandin, the main water-soluble protein in almonds, inducing oxidation by malondialdehyde (MDA) were investigated. The results showed that the content of carbonyl group increased from 5.23 to 33.25 nmol mg−1 of protein with the increase in MDA concentration (P < 0.05). However, the sulphydryl content, surface hydrophobicity, particle size and the absolute value of ζ-potential first increased and then decreased. Fourier-transformed infrared spectroscopy (FT-IR) confirmed that the structure of amandin changed from order to disorder. Fluorescence spectroscopic analysis revealed that mild oxidation (0–0.1 mmol L−1 MDA) exposed hydrophobic groups of the protein. Sodium dodecyl sulphate polyacrylamide gel electrophoresis (SDS-PAGE) suggested that protein oxidation promoted crosslinking between protein molecules. Furthermore, protein oxidation markedly declined the total amino acid content of amandin (P < 0.05). In conclusion, MDA oxidation changed the structure and amino acid content of amandin, and caused the protein aggregate and crosslink through hydrophobic interaction and electrostatic interaction. 相似文献